Enhanced mid-IR luminescence of Tm3+ ions in Ga2S3 nanocrystals embedded chalcohalide glass ceramics
Identifieur interne : 000933 ( Main/Exploration ); précédent : 000932; suivant : 000934Enhanced mid-IR luminescence of Tm3+ ions in Ga2S3 nanocrystals embedded chalcohalide glass ceramics
Auteurs : Shixun Dai [République populaire de Chine] ; Changgui Lin [République populaire de Chine] ; Feifei Chen [République populaire de Chine] ; Xianghua Zhang [France] ; Chao Liu [Corée du Sud] ; Kai Xu [Corée du Sud] ; Jong Heo [Corée du Sud] ; Xiang Shen [République populaire de Chine] ; Xunsi Wang [République populaire de Chine]Source :
- Journal of Non-Crystalline Solids [ 0022-3093 ] ; 2011-06.
English descriptors
Abstract
Chalcohalide glass with a composition of 65GeS2-25Ga2S3-10CsI (in mol%) doped with 0.6 wt% Tm3+ ions was prepared by conventional melt-quench method. By heat treating the precursor glass at 20 °C above its glass transition temperature Tg for different durations, IR transparent glass ceramics were obtained. X-ray diffraction (XRD) and scanning electron microscope (SEM) showed that Ga2S3 crystallites were precipitated after heat treatment and their grain sizes were in nano-scale and increased with the elongation of heat treated time. Mid-IR luminescence properties of the glass and transparent glass ceramic samples were investigated. The emissions at 2.3 and 3.8 μm corresponding to optical transitions of 3H4 → 3H5 and 3H5 → 3F4 of Tm3+ ions were significantly enhanced by the presence of Ga2S3 nanocrystals and reached a maximum after 8 hours treatment.
Url:
DOI: 10.1016/j.jnoncrysol.2010.11.063
Affiliations:
- Corée du Sud, France, République populaire de Chine
- Région Bretagne
- Rennes
- Université de Rennes 1, Université européenne de Bretagne
Links toward previous steps (curation, corpus...)
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Le document en format XML
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last="Shen">Xiang Shen</name><affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-230386" status="INCOMING"><orgName>Faculty of Information Science and Engineering</orgName><desc><address><addrLine>Ningbo University, Ningbo 315211, PR China</addrLine><country key="CN"></country></address></desc><listRelation><relation active="#struct-322379" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-322379" type="direct"><org type="institution" xml:id="struct-322379" status="INCOMING"><orgName>NINGBO UNIVERSITY</orgName><desc><address><country key="FR"></country></address></desc></org></tutelle></tutelles></hal:affiliation><country>République populaire de Chine</country></affiliation></author><author><name sortKey="Wang, Xunsi" sort="Wang, Xunsi" uniqKey="Wang X" first="Xunsi" last="Wang">Xunsi Wang</name><affiliation wicri:level="1"><hal:affiliation type="laboratory" xml:id="struct-230386" status="INCOMING"><orgName>Faculty of Information Science and Engineering</orgName><desc><address><addrLine>Ningbo University, Ningbo 315211, PR China</addrLine><country key="CN"></country></address></desc><listRelation><relation active="#struct-322379" type="direct"></relation></listRelation><tutelles><tutelle active="#struct-322379" type="direct"><org type="institution" xml:id="struct-322379" status="INCOMING"><orgName>NINGBO UNIVERSITY</orgName><desc><address><country key="FR"></country></address></desc></org></tutelle></tutelles></hal:affiliation><country>République populaire de Chine</country></affiliation></author></analytic><idno type="DOI">10.1016/j.jnoncrysol.2010.11.063</idno><series><title level="j">Journal of Non-Crystalline Solids</title><idno type="ISSN">0022-3093</idno><imprint><date type="datePub">2011-06</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="mix" xml:lang="en"><term>Chalcohalide glasses</term><term>Glass ceramic</term><term>Mid-infrared</term><term>Thulium ions</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Chalcohalide glass with a composition of 65GeS2-25Ga2S3-10CsI (in mol%) doped with 0.6 wt% Tm3+ ions was prepared by conventional melt-quench method. By heat treating the precursor glass at 20 °C above its glass transition temperature Tg for different durations, IR transparent glass ceramics were obtained. X-ray diffraction (XRD) and scanning electron microscope (SEM) showed that Ga2S3 crystallites were precipitated after heat treatment and their grain sizes were in nano-scale and increased with the elongation of heat treated time. Mid-IR luminescence properties of the glass and transparent glass ceramic samples were investigated. The emissions at 2.3 and 3.8 μm corresponding to optical transitions of 3H4 → 3H5 and 3H5 → 3F4 of Tm3+ ions were significantly enhanced by the presence of Ga2S3 nanocrystals and reached a maximum after 8 hours treatment.</div></front></TEI><affiliations><list><country><li>Corée du Sud</li><li>France</li><li>République populaire de Chine</li></country><region><li>Région Bretagne</li></region><settlement><li>Rennes</li></settlement><orgName><li>Université de Rennes 1</li><li>Université européenne de Bretagne</li></orgName></list><tree><country name="République populaire de Chine"><noRegion><name sortKey="Dai, Shixun" sort="Dai, Shixun" uniqKey="Dai S" first="Shixun" last="Dai">Shixun Dai</name></noRegion><name sortKey="Chen, Feifei" sort="Chen, Feifei" uniqKey="Chen F" first="Feifei" last="Chen">Feifei Chen</name><name sortKey="Lin, Changgui" sort="Lin, Changgui" uniqKey="Lin C" first="Changgui" last="Lin">Changgui Lin</name><name sortKey="Shen, Xiang" sort="Shen, Xiang" uniqKey="Shen X" first="Xiang" last="Shen">Xiang Shen</name><name sortKey="Wang, Xunsi" sort="Wang, Xunsi" uniqKey="Wang X" first="Xunsi" last="Wang">Xunsi Wang</name></country><country name="France"><region name="Région Bretagne"><name sortKey="Zhang, Xianghua" sort="Zhang, Xianghua" uniqKey="Zhang X" first="Xianghua" last="Zhang">Xianghua Zhang</name></region></country><country name="Corée du Sud"><noRegion><name sortKey="Liu, Chao" sort="Liu, Chao" uniqKey="Liu C" first="Chao" last="Liu">Chao Liu</name></noRegion><name sortKey="Heo, Jong" sort="Heo, Jong" uniqKey="Heo J" first="Jong" last="Heo">Jong Heo</name><name sortKey="Xu, Kai" sort="Xu, Kai" uniqKey="Xu K" first="Kai" last="Xu">Kai Xu</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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